Optimized interaction parameters for metal-doped endohedral fullerene
نویسندگان
چکیده
منابع مشابه
Photoionization of the endohedral fullerene ions
The first experimental results on photoionization of mass-selected endohedral Sc3N@C + 80 and Ce@C + 82 fullerene ions are reported. The merged-beams technique was employed to measure photo-ion yield spectra as well as absolute cross sections. Comparing the results of endohedral fullerenes with those obtained using ”empty” C+80 and C + 82 ions provides insight into the mutual influence of the f...
متن کاملFullerene doped glasses
Optical glasses doped with a fullerene mixture of C60/C70 were made in our lab. Three peaks, corresponding to C60 , C70 , and a modified fullerene ~possibly its oxide!, respectively, were found in the chromatogram of high performance liquid chromatography ~HPLC! analysis of the 0.1-wt % fullerene doped phosphate glass. Depending on the doping procedure and impurity, weak to strong interacting b...
متن کاملCryogenic NMR spectroscopy of endohedral hydrogen-fullerene complexes.
We have observed 1H NMR spectra of hydrogen molecules trapped inside modified fullerene cages under cryogenic conditions. Experiments on static samples were performed at sample temperatures down to 4.3 K, while magic-angle-spinning (MAS) experiments were performed at temperatures down to 20 K at spinning frequencies of 15 kHz. Both types of NMR spectra show a large increase in the intramolecula...
متن کاملSublimation of the endohedral fullerene Er(3)N@C(80).
The heat of sublimation of the endohedral metallofullerene Er(3)N@C(80) was measured via Knudsen effusion mass spectrometry. The large molecule consists of a C(80) fullerene cage which is stabilized by a complex of three erbium atoms bounded to a nitrogen atom and has a mass of 1475 amu. The mass spectrum at a temperature of 1045 K and the relative intensities of the thermal fractions of Er(3)N...
متن کاملSolid-state NMR of endohedral hydrogen-fullerene complexes.
We present an overview of solid-state NMR studies of endohedral H(2)-fullerene complexes, including (1)H and (13)C NMR spectra, (1)H and (13)C spin relaxation studies, and the results of (1)H dipole-dipole recoupling experiments. The available data involves three different endohedral H(2)-fullerene complexes, studied over a wide range of temperatures and applied magnetic fields. The symmetry of...
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ژورنال
عنوان ژورنال: Applied Nanoscience
سال: 2017
ISSN: 2190-5509,2190-5517
DOI: 10.1007/s13204-017-0556-0